Synthesis and characterization of Fe3O4@SiO2 sub-nano core/shell with SiO2 derived from rice husk ash
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Từ khóa:
Fe3O4@SiO2
core-shell structure
saturation magnetization
rice husk ash
Tóm tắt
This study aims to synthesize and characterize Fe3O4@SiO2 sub-nanoparticles (SNPs) with high saturation magnetization (SM). The research process was conducted in simple and environmentally friendly conditions. The results of ultraviolet-visible (UV-Vis) spectroscopy and X-ray diffraction (XRD) analysis presented that the Fe3O4@SiO2 SNPs were well formed and the phase change of Fe3O4 NPs did not happen in Fe3O4@SiO2 SNPs. Transmission electron microscope (TEM) analysis showed that the Fe3O4@SiO2 SNPs are in a fairly spherical shape with a core/shell structure and a diameter in a range of 100 nm to 500 nm. Fourier transform infrared spectrometry (FT-IR) spectra of Fe3O4@SiO2 SNPs presented some absorption peaks indicating the existence of Si-O-Si, O-Si-O, Fe-O and Fe-O-Si. The SM of Fe3O4 particles and Fe3O4@SiO2 SNPs determined via vibrating sample magnetometer (VSM) were 50.9 emu.g−1 and 19.5 emu.g−1, respectively. All the above results provide clear evidence that the Fe3O4 particles were coated by SiO2 to form sub-nano core/shell with great SM.
Tài liệu tham khảo
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[1] J.H. Lee, Y.w. Jun, S.I. Yeon, J.S. Shin, J. Cheon, “Dual‐mode nanoparticle probes for high‐performance magnetic resonance and fluorescence imaging of neuroblastoma”, Angewandte Chemie, 118(48), 2006, 8340-8342.
[2] F. Hu, L. Wei, Z. Zhou, Y. Ran, Z. Li, M. Gao, “Preparation of biocompatible magnetite nanocrystals for in vivo magnetic resonance detection of cancer”, Advanced Materials, 18(19), 2006, 2553-2556.
[3] N. Nasongkla, E. Bey, J. Ren, H. Ai, C. Khemtong, J.S. Guthi, S.-F. Chin, A.D. Sherry, D.A. Boothman, J. Gao, “Multifunctional polymeric micelles as cancer-targeted, MRI-ultrasensitive drug delivery systems”, Nano letters, 6(11), 2006, 2427-2430.
[4] S. Kumar, A.K. Jana, I. Dhamija, Y. Singla, M. Maiti, “Preparation, characterization and targeted delivery of serratiopeptidase immobilized on amino-functionalized magnetic nanoparticles”, European Journal of Pharmaceutics and Biopharmaceutics, 85(3), 2013, 413-426.
[5] J. Jordan, C.S. Kumar, C. Theegala, “Preparation and characterization of cellulase-bound magnetite nanoparticles”, Journal of Molecular Catalysis B: Enzymatic, 68(2), 2011, 139-146.
[6] Y.-T. Zhu, X.-Y. Ren, Y.-M. Liu, Y. Wei, L.-S. Qing, X. Liao, “Covalent immobilization of porcine pancreatic lipase on carboxyl-activated magnetic nanoparticles: characterization and application for enzymatic inhibition assays”, Materials Science and Engineering: C, 38, 2014, 278-285.
[7] A.H. Lu, E.e.L. Salabas, F. Schüth, “Magnetic nanoparticles: synthesis, protection, functionalization, and application”, Angewandte Chemie International Edition, 46(8), 2007, 1222-1244.
[8] C. Hui, C. Shen, J. Tian, L. Bao, H. Ding, C. Li, Y. Tian, X. Shi, H.-J. Gao, “Core-shell Fe3O4@SiO2 nanoparticles synthesized with well-dispersed hydrophilic Fe3O4 seeds”, Nanoscale, 3(2), 2011, 701-705.
[9] Y. Lu, Y. Yin, B.T. Mayers, Y. Xia, “Modifying the surface properties of superparamagnetic iron oxide nanoparticles through a sol−gel approach”, Nano letters, 2(3), 2002, 183-186.
[10] G. Chandrasekaran, P.N. Sebastian, “Magnetic study of ZnxMg1− xFe2O4 mixed ferrites”, Materials Letters, 37(1-2), 1998, 17-20.
[11] W.C. Kim, S.J. Kim, S.W. Lee, C.S. Kim, “Growth of ultrafine NiZnCu ferrite and magnetic properties by a sol–gel method”, Journal of magnetism and magnetic materials, 226, 2001, 1418-1420.
[12] A. Ataie, S. Heshmati-Manesh, “Synthesis of ultra-fine particles of strontium hexaferrite by a modified co-precipitation method”, Journal of the European Ceramic Society, 21(10-11), 2001, 1951-1955.
[13] S.-H. Yu, T. Fujino, M. Yoshimura, “Hydrothermal synthesis of ZnFe2O4 ultrafine particles with high magnetization”, Journal of Magnetism and Magnetic Materials, 256(1-3), 2003, 420-424.
[14] X. Lu, H. Mao, D. Chao, W. Zhang, Y. Wei, “Ultrasonic synthesis of polyaniline nanotubes containing Fe3O4 nanoparticles”, Journal of Solid State Chemistry, 179(8), 2006, 2609-2615.
[15] R. Qiao, C. Yang, M. Gao, “Superparamagnetic iron oxide nanoparticles: from preparations to in vivo MRI applications”, Journal of Materials Chemistry, 19(35), 2009, 6274-6293.
[16] Z. Xu, Y. Hou, S. Sun, “Magnetic core/shell Fe3O4/Au and Fe3O4/Au/Ag nanoparticles with tunable plasmonic properties”, Journal of the American Chemical Society, 129(28), 2007, 8698-8699.
[17] J. Ge, Q. Zhang, T. Zhang, Y. Yin, “Core–satellite nanocomposite catalysts protected by a porous silica shell: controllable reactivity, high stability, and magnetic recyclability”, Angewandte Chemie International Edition, 47(46), 2008, 8924-8928.
[18] Y. Deng, C. Deng, D. Qi, C. Liu, J. Liu, X. Zhang, D. Zhao, “Synthesis of core/shell colloidal magnetic zeolite microspheres for the immobilization of trypsin”, Advanced Materials, 21(13), 2009, 1377-1382.
[19] A.-L. Morel, S.I. Nikitenko, K. Gionnet, A. Wattiaux, J. Lai-Kee-Him, C. Labrugere, B. Chevalier, G. Deleris, C. Petibois, A. Brisson, “Sonochemical approach to the synthesis of Fe3O4@SiO2 core−shell nanoparticles with tunable properties”, ACS nano, 2(5), 2008, 847-856.
[20] W. Stöber, A. Fink, E. Bohn, “Controlled growth of monodisperse silica spheres in the micron size range”, Journal of colloid and interface science, 26(1), 1968, 62-69.
[21] X. Jiang, T. Herricks, Y. Xia, “Monodispersed spherical colloids of titania: synthesis, characterization, and crystallization”, Advanced Materials, 15(14), 2003, 1205-1209.
[22] S.C.W. Sakti, D. Siswanta, Adsorption of gold (III) on ionic imprinted amino-silica hybrid prepared from rice hull ash, Pure and Applied Chemistry 85(1) (2012) 211-223.
[23] N.T. Tuấn, N.H.M. Phú, H.N.T. Tân, P.T.B. Thảo, N.T.K. Chi, L.V. Nhạn, N.T. Tuân, T.X. Anh, Tổng hợp hạt nano SiO2 từ tro vỏ trấu bằng phương pháp kết tủa, Tạp chí Khoa học Trường Đại học Cần Thơ (2014) 120-124.
[24] N. Gan, P. Xiong, J. Wang, T. Li, F. Hu, Y. Cao, L. Zheng, “A novel signal-amplified immunoassay for the detection of C-reactive protein using HRP-doped magnetic nanoparticles as labels with the electrochemical quartz crystal microbalance as a detector”, Journal of analytical methods in chemistry, 2013.
[25] Y. Wang, X. Peng, J. Shi, X. Tang, J. Jiang, W. Liu, “Highly selective fluorescent chemosensor for Zn2+ derived from inorganic-organic hybrid magnetic core/shell Fe3O4@SiO2 nanoparticles”, Nanoscale research letters, 7(1), 2012, 86.
[26] N. Basavegowda, K.B.S. Magar, K. Mishra, Y.R. Lee, “Green fabrication of ferromagnetic Fe3O4 nanoparticles and their novel catalytic applications for the synthesis of biologically interesting benzoxazinone and benzthioxazinone derivatives”, New Journal of Chemistry, 38(11), 2014, 5415-5420.
[27] S. Venkateswaran, R. Yuvakkumar, V. Rajendran, “Nano silicon from nano silica using natural resource (RHA) for solar cell fabrication”, Phosphorus, Sulfur, and Silicon and the Related Elements, 188(9), 2013, 1178-1193.
[28] M. Choolaei, A.M. Rashidi, M. Ardjmand, A. Yadegari, H. Soltanian, “The effect of nanosilica on the physical properties of oil well cement”, Materials Science and Engineering: A, 538, 2012, 288-294.
[29] S. Wang, J. Tang, H. Zhao, J. Wan, K. Chen, “Synthesis of magnetite–silica core–shell nanoparticles via direct silicon oxidation”, Journal of colloid and interface science, 432, 2014, 43-46.
[30] N. Nuryono, N.M. Rosiati, B. Rusdiarso, S.C.W. Sakti, S. Tanaka, Coating of magnetite with mercapto modified rice hull ash silica in a one-pot process, SpringerPlus 3(1) (2014) 515.
[31] Y. Chen, Z. Peng, L.X. Kong, M.F. Huang, P.W. Li, “Natural rubber nanocomposite reinforced with nano silica”, Polymer Engineering & Science, 48(9), 2008, 1674-1677.
[32] A.M. Said, M.S. Zeidan, M. Bassuoni, Y. Tian, “Properties of concrete incorporating nano-silica”, Construction and Building Materials, 36, 2012, 838-844.
[33] F. Subhan, S. Aslam, Z. Yan, M. Khan, U. Etim, M. Naeem, “Effective adsorptive performance of Fe3O4@SiO2 core-shell spheres for methylene blue: kinetics, isotherm and mechanism”, Journal of Porous Materials, 2019, 1-10.
[34] Z.U. Rahman, T. Zhang, S. Cui, D. Wang, “Preparation and characterization of magnetic nanocomposite catalysts with double Au nanoparticle layers”, RSC Advances, 5(121), 2015, 99697-99705.
[35] L. Wang, C. Shen, Y. Cao, “PVP modified Fe3O4@SiO2 nanoparticles as a new adsorbent for hydrophobic substances”, Journal of Physics and Chemistry of Solids, 133, 2019, 28-34.
[36] M. Mostafaei, S.N. Hosseini, M. Khatami, A. Javidanbardan, A.A. Sepahy, E. Asadi, “Isolation of recombinant Hepatitis B surface antigen with antibody-conjugated superparamagnetic Fe3O4/SiO2 core-shell nanoparticles”, Protein expression and purification, 145, 2018, 1-6.
[37] M. Gao, W. Li, J. Dong, Z. Zhang, B. Yang, Synthesis and characterization of superparamagnetic Fe3O4@SiO2 core-shell composite nanoparticles, World Journal of Condensed Matter Physics 1(02) (2011) 49.
[38] Y. Zhang, Q. Xu, S. Zhang, J. Liu, J. Zhou, H. Xu, H. Xiao, J. Li, Preparation of thiol-modified Fe3O4@SiO2 nanoparticles and their application for gold recovery from dilute solution, Separation and Purification Technology 116 (2013) 391-397.
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Jun 30, 2020
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Cách trích dẫn
Luong Huynh Vu Thanh, Tran Nguyen Phuong Lan, Tran Thi Bich Quyen, Ha Quoc Nam, Le Phuoc Bao Tho. “Synthesis and Characterization of Fe3O4@SiO2 Sub-Nano core/Shell With SiO2 Derived from Rice Husk Ash”. Tạp Chí Khoa học Và Công nghệ - Đại học Đà Nẵng, vol 18, số p.h 6, Tháng Sáu 2020, tr 52-56, doi:10.31130/jst-ud2020-178E.
