Effect of sulfate and chloride solutions on the compressive and flexural strengths of mortar incorporating spent coffee grounds




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Author
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Van-Dung NguyenHong Duc University, Thanh Hoa City, VietnamDang-Nguyen NguyenHanoi University of Civil Engineering, Ha Noi, Vietnam
Từ khóa:
Tóm tắt
Vietnam is a major coffee consumer, generating large amounts of spent coffee grounds (SCG), typically discarded as waste. This creates environmental concerns but also offers potential for resource reuse. Meanwhile, Vietnam’s construction industry faces a shortage of natural river sand. The study explores the potential of using SCG as a partial replacement for natural sand in mortar production, aiming to support sustainable development. The effect of varying SCG contents on the compressive and flexural strengths of mortar under different aggressive environments was examined, including immersion in water, 5% NaCl solution, 5% Na2SO4 solution, and a mixed 5% NaCl-Na2SO4 solution. Results revealed that both compressive and flexural strengths increased over time; however, higher SCG content resulted in a gradual decrease in both. Furthermore, immersion in different solutions influenced the mortar’s strength, with tap water proving the most beneficial for compressive strength, while 5% Na2SO4 solution showed the greatest effect on flexural strength.
Tài liệu tham khảo
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[1] V. Atkinson, “Used coffee grounds make concrete 30% stronger”, Livescience.com, Sep 7, 2023 [Online]. Available: https://www.livescience.com/chemistry/used-coffee-grounds-make-concrete-30-stronge [Accessed May 06, 2025].
[2] T. Means and M. Lalanilla, “Greenhouse gases: Causes, sources and environmental effects”, Livescience.com, June 10, 2021 [Online]. Available: https://www.livescience.com/37821-greenhouse-gases.html [Accessed May 06, 2025].
[3] C. Santos, J. Fonseca, J. L. Pereira, L. Ferreira, J. Coutinho, and H. Trindade, “Effect of lignocellulosic and phenolic compounds on ammonia, nitric oxide and greenhouse gas emissions during composting”, J. Clean. Prod., vol. 171, pp. 548-556, 2018. https://doi.org/10.1016/j.jclepro.2017.10.050
[4] A. Arulrajah, F. Maghoolpilehrood, M. M. Disfani, and S. Horpibulsuk, “Spent coffee grounds as a non-structural embankment fill material: engineering and environmental considerations”, J. Clean. Prod., vol. 72, pp. 181-186, 2014. https://doi.org/10.1016/j.jclepro.2014.03.010
[5] D. Eliche-Quesada et al., “The use of different forms of waste in the manufacture of ceramic bricks”, Appl. Clay. Sci., vol. 52, no. 3, pp. 270-276, 2011. https://doi.org/10.1016/j.clay.2011.03.003
[6] D. Eliche-Quesada, L. Pérez-Villarejo, F. J. Iglesias-Godino, C. Martínez-García, and F. A. Corpas-Iglesias, “Incoroporation of coffee grounds into clay brick production”, Adv. Appl. Ceram., vol. 110, no. 4, pp. 225-232, 2011. https://doi.org/10.1179/1743676111Y.0000000006
[7] F. Andreola et al., “Spent coffee grounds in the production of lightweight clay ceramic aggregates in view of urban and agricultural sustainable development”, Materials, vol. 12, no. 21, p. 3581, 2019. https://doi.org/10.3390/ma12213581
[8] B. Y. Yun, H. M. Cho, Y. U. Kim, S. C. Lee, U. Berardi, and S. Kim, “Circular reutilization of coffee waste for sound absorbing panels: A perspective on material recycling”, Environ. Res., vol. 184, p. 109281, 2020. https://doi.org/10.1016/j.envres.2020.109281
[9] A. Lachheb et al., “Thermal insulation improvement in construction materials by adding spent coffee grounds: An experimental and simulation study”, J. Clean. Prod., vol. 209, pp. 1411-1419, 2019. https://doi.org/10.1016/j.jclepro.2018.11.140
[10] M. Saberian et al., “Recycling of spent coffee grounds in construction materials: A review”, J. Clean. Prod., vol. 289, p. 125837, 2021. https://doi.org/10.1016/j.jclepro.2021.125837
[11] S. Na, S. Lee, and S. Youn, “Experiment on activated carbon manufactured from waste coffee grounds on the compressive strength of cement mortars”, Symmetry, vol. 13, no. 4, p. 619, 2021. https://doi.org/10.3390/sym13040619
[12] R. Roychand, S. Kilmartin-Lynch, M. Saberian, J. Li, G. Zhang, and C. Q. Li, “Transforming spent coffee grounds into a valuable resource for the enhancement of concrete strength”, J. Clean. Prod., vol. 419, p. 138205, 2023. https://doi.org/10.1016/j.jclepro.2023.138205
[13] J. D. Lee, J. Kim, and S. Lee, “Study of recycled spent coffee grounds as aggregates in cementious materials”, Recent Progress in Materials, vol. 5, no. 1, p. 007, 2023. https://doi.org/10.21926/rpm.2301007
[14] A. Neville, “The confused world of sulfate attack on concrete”, Cem. Concr. Res., vol. 34, no. 8, pp. 1275–1296, 2004. https://doi.org/10.1016/j.cemconres.2004.04.004
[15] G. G. Xu, S. C. Gu, X. D. Wang, H. Wang, and S. B. Zhu, “Grouting to prevent sulfate corrosion on coal mine shaft”, KSCE J. Civ. Eng., vol. 25, no. 11, pp. 4133–4143, 2021. https://doi.org/10.1007/s12205-021-1761-7
[16] O.S.B. Al-Amoudi, “Attack on plain and blended cements exposed to aggressive sulfate environments”, Cem. Concr. Compos., vol. 24, no. 3–4, pp. 305–316, 2002. https://doi.org/10.1016/S0958-9465(01)00082-8
[17] A.M. Hossack and M.D.A. Thomas, “The effect of temperature on the rate of sulfate attack of Portland cement blended mortars in Na2SO4 solution”, Cem. Concr. Res., vol. 73, pp. 136–142, 2015. https://doi.org/10.1016/j.cemconres.2015.02.024
[18] R. He, S. Zheng, V.J.L. Gan, Z. Wang, J. Fang, and Y. Shao, “Damage mechanism and interfacial transition zone characteristics of concrete under sulfate erosion and dry-wet cycles”, Constr. Build. Mater., vol. 255, p. 119340, 2020. https://doi.org/10.1016/j.conbuildmat.2020.119340
[19] J. Du, G. Li, and J. Wu, “Concrete sulfate corrosion coupled with hydraulic pressure”, Mar. Georesour. Geotechnol., vol. 38, no. 1, pp. 40–47, 2020. https://doi.org/10.1080/1064119X.2018.1550828
[20] K. Sotiriadis, E. Nikolopoulou, and S. Tsivilis, “Sulfate resistance of limestone cement concrete exposed to combined chloride and sulfate environment at low temperature”, Cement Concr. Compos., vol. 34, no. 8, pp. 903–910, 2012. https://doi.org/10.1016/j.cemconcomp.2012.05.006
[21] N. D. Nguyen, M. T. Hong, N. V. Dung, “Strength and durability of mortar containing spent coffee grounds as a part of fine aggregate”, Vietnam Journal of Science and Technology−MOST, vol. 67, no. 6., pp. 45-51, 2025 (in Vietnamese). https://doi.org/10.31276/VJST.67(6).45-51
[22] L. F. Ballesteros, J. A. Teixeira, and S. I. Massatto, “Chemical, functional, and structural properties of spent coffee grounds and coffee silverskin”, Food Bioprocess Technol., vol. 7, pp. 3493-3503, 2014. https://doi.org/10.1007/s11947-014-1349-z
[23] T. P. Huynh, S. H. Ngo, “Waste incineration bottom ash as a fine aggregate in mortar: An assessment of engineering properties, durability, and microstructure”, J. Build. Eng., vol. 52, p. 1044446, 2022. https://doi.org/10.1016/j.jobe.2022.104446
[24] Mortar for masonry − Specifications, TCVN 4314:2022, 2022.
[25] Mortar for masonry − Test methods, TCVN 3121:2022, 2022.
[26] J. B. Camacho, S. M. Abdelkader, E. R. Pozo, and T. Moragues, “The influence of ion chloride on concretes made with sulfate-resistant cements and mineral admixtures”, Constr. Build. Mater., vol. 70, pp. 483–493, 2014. https://doi.org/10.1016/j.conbuildmat.2014.07.109
[27] J. Du, Z. Tang, G. Li, H. Yang, and L. Li, “Key inhibitory mechanism of external chloride ions on concrete sulfate attack”, Constr. Build. Mater., vol. 225, pp. 611–619, 2019. https://doi.org/10.1016/j.conbuildmat.2019.07.263
[28] J. Du, Z. Liu, J. Sun, G. Li, X. Wu, G. Li, Y. Lv, and K. Wang, “Enhancing concrete sulfate resistance by adding NaCl”, Constr. Build. Mater., vol. 322, p. 126370, 2022. https://doi.org/10.1016/j.conbuildmat.2022.126370
[29] M. Zhang, J. Chen, Y. Lv, D. Wang, and J. Ye, “Study on the expansion of concrete under attack of sulfate and sulfate-chloride ions”, Constr. Build. Mater., vol. 39, pp. 26-32, 2013. https://doi.org/10.1016/j.conbuildmat.2012.05.003
[30] R. Gopalakrishnan and R. Jeyalakshmi, “The effects on durability and mechanical properties of multiple nano and micro additive OPC mortar exposed to combined chloride and sulfate attack”, Mater. Sci. Semicond. Process., vol. 106, p. 104772, 2020. https://doi.org/10.1016/j.mssp.2019.104772
[31] J. Zuquan, S. Wei, Z. Yunsheng, J. Jinyang, and L. Jianzhong, “Interaction between sulfate and chloride solution attack of concrete with and without fly ash”, Cem. Concr. Res., vol. 37, pp. 1223-1232, 2007. https://doi.org/10.1016/j.cemconres.2007.02.016