Degradation of chlothianidin from Dantutso 50WG in electrochemical process: Kinetics and role of reactive species

https://doi.org/10.31130/ud-jst.2022.027E
Tóm tắt: 56 | PDF: 36

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Author

  • Hoang Nguyen Tien
    The University of Danang - University of Science and Education

Từ khóa:

chlothianidin
the second-order rate constant
electrochemical degradation
kinetic degradation
competition kinetics method

Tóm tắt

The kinetic degradation of clothianidin (CLO) (in Dantuso 50 WG) during electrochemical oxidation (EO) process using sulfate- and chloride-supporting electrolytes was comprehensively investigated. The degradation of CLO was not due to direct electron oxidation, but was mainly due to •OH and other radicals generated from supporting electrolytes. The degradation of CLO was significantly inhibited when increasing the concentration of nitrobenzene (NB), methanol (MeOH) and benzoic acid (BA). The second-order rate constant of •OH toward CLO was determined to be 3.23×109 M-1 s-1 using competition kinetics method. When SO42- and Cl- were used as supporting electrolytes, the degradation of CLO by •OH was the same with kCLO = 0.0084 min-1. Meanwhile, the higher removal of CLO in SO42--supporting electrolyte was due to the contribution of (SO4•-/S2O82-) more than that of (Cl•/HClO/ClO-).

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Nguyen Tien, H. “Degradation of Chlothianidin from Dantutso 50WG in Electrochemical Process: Kinetics and Role of Reactive Species”. Tạp Chí Khoa học Và Công nghệ - Đại học Đà Nẵng, vol 20, số p.h 6.1, Tháng Sáu 2022, tr 35-40, doi:10.31130/ud-jst.2022.027E.

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