A study on synthesis and evaluation of catalytic activity for hydrogen evolution reaction of Ni-MOF materials on nickel foam using ligand 2-methylimidazole
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Keywords:
Metal-organic framework
Ni-MOF
nickel foam
ligand 2-methylimidazole
hydrogen evolution reaction
Abstract
The metal-organic framework Ni-MOF/NF was synthesized by solvothermal approach using the organic ligand 2-methylimidazole. The obtained material was characterized using infrared (IR) spectroscopy, X-ray diffraction (XRD), EDX spectroscopy, and SEM images. The Ni-MOF/NF materials were employed as a catalyst for the hydrogen evolution reaction (HER) in NaOH 1 M solution. It was shown that Ni-MOF/NF significantly reduces the overpotential and Tafel slope for the hydrogen evolution reaction. The conditions for the synthesis of material were studied. Experimental results show that the materials synthesized from nickel nitrate and ligand 2-methylimidazole at a molar ratio of 1:8 with heating at 180oC for 8 h have good catalytic activity for the HER. In addition, the Ni-MOF/NF catalyst exhibits excellent catalytic durability and stability, as demonstrated by stable catalytic performance after 10 h operation.
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Published
Aug 31, 2023
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Vũ Thị Duyên, Ngô Thị Mỹ Bình, Đoàn Văn Dương, Võ Thắng Nguyên, Đinh Văn Tạc, Trịnh Ngọc Đạt, Lê Vũ Trường Sơn, Lê Nhật Phương, Nguyễn Thị Trà Giang, Mai Đăng Nhật Hưng, Doãn Thị Hà Ngọc, and Đinh Nguyễn Đại Phú. “A Study on Synthesis and Evaluation of Catalytic Activity for Hydrogen Evolution Reaction of Ni-MOF Materials on Nickel Foam Using Ligand 2-Methylimidazole”. The University of Danang - Journal of Science and Technology, vol. 21, no. 8.2, Aug. 2023, pp. 80-85, https://jst-ud.vn/jst-ud/article/view/8501.
