Performance of predictive approaches for the viscosity of binary liquid mixtures of 1-alcohols
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Author
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Nguyen Thanh BinhThe University of Danang - University of Science and Technology, Danang, Vietnam
Từ khóa:
Tóm tắt
The objective of this study is to evaluate the predictive performance of three semi-theoretical approaches for modeling viscosity of binary liquid mixtures composed of 1-alcohols. For the mixtures that contain 1-alcohols with a similar number of carbon atoms, three schemes including the Rough Hard-Sphere model, the McAllister model, and UNIFAC-VISCO were demonstrated to be able to reproduce the mixture viscosity with an average deviation of 5%. For highly asymmetrical mixtures without the presence of small molecules, only McAllister-type model successfully reproduced the experimental values. The prediction done by the Rough Hard-Sphere model on the basis of using simple mixing rules for characteristic parameters indicated that this model should be further modified to improve its predictive capability.
Tài liệu tham khảo
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